First up Superman, must say the most hansom Superhero of them all all dressed i
n his cape and sporting the primary colours better then any other. He made geeky office nerd, a new Kind of Hot when it came to men. 
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Batman, Going for the all black look, could never go wrong with that,
as the secret to a good sence of style is being able to be simple put together. He might look a lil on the harsh side butt hen again when you dont know what to wear, go all black and pic your fave accerosies, inoder to stand out. I Guess his would be the Batmobile.
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Easiest way to incoporate the look
(Vivienne Westwood)
Dr Freeze is wan cold dude, but with the right taste, you could look Hot taking him as an insperation.
Although this look might not be necassary, the snowflake look by Ninna Ricci however is a more softer, warmer look to this villains look. 
Spiderman, Cobwebs used to be a thing you find in old houses, but to pull this look off without looking goths, 
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you could always go for black floral printed lace, which is on of this seasons trends, so be sure to pick up a beautifule black lace dress!
(Prada fall/winter 08)
CatWoman might as well coined the BodyCon, her Leather Catsuite is simply a second skin being skin tight and shiny,
sadly walking around with an outfit with a description like thatyour bound to called something nasty, but sometimes, if worn right it might just work. 
Topshop, H&M and Balenciaga
Iron Man, yepp that pretty mucyh sums it up.....
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to be continued...........